期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 4, 期 4, 页码 488-507出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200800361
关键词
asymmetric catalysis; Bronsted bases; guanidines; hydrogen bonding; organocatalysis
资金
- ARF [R-143-000-337-112]
- Kiang Ai Kim scholarship
Chiral guanidine catalysts share common characteristics such as high pK(a) values and dual hydrogen-bonding modes of activation, and high catalytic activities and enantioselectivities can often be achieved. The utilization of guanidines as catalysts has been growing at a steady pace. In the past few years, it has attracted tremendous attention through several landmark achievements. This article highlights the development of chiral guanidine catalysis in asymmetric synthesis.
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