期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 4, 期 8, 页码 1184-1195出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200900080
关键词
asymmetric catalysis; chiral ligands; functionalization; ionic liquids; organocatalysis
资金
- Natural Science Foundation of China [20421202, 20632060, 20702052]
- Ministry of Science and Technology [2008CB617501]
- Chinese Academy of Sciences
By judiciously anchoring functional groups onto chiral ionic liquids, functionalized chiral ionic liquids (FCILs) are emerging as a new type of asymmetric organocatalysts and nonclassical chiral ligands. This Focus Review highlights the applications of FCILs from the viewpoint of asymmetric catalysis. We focus mainly on the de novo designed and synthesized FCILs which likely still maintain the typical ionic liquids properties, and in a few cases relevant ionic liquid immobilized chiral catalysts are briefly discussed.
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