期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 4, 期 7, 页码 1078-1083出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200900111
关键词
alkenes; alkenylsilanes; cobalt; Grignard reagents; isomerization
资金
- JSPS
Treatment of 1-alkenes with dimethylphenylsilylmethylmagnesium chloride in the presence of a cobalt-NHC complex in dioxane at 50 degrees C or higher provides the corresponding (E)-2-alkenes selectively. The isomerization is applicable to the stereoselective synthesis of (E)-crotylsilanes and (E)-1-propenylsilanes from the corresponding homoallylsilanes and allylsilanes, respectively.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据