期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 3, 期 10, 页码 1750-1770出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200800196
关键词
asymmetric catalysis; green chemistry; homogenous catalysis; hydrogenation; organocatalysis
Asymmetric transfer hydrogenation has become a practically useful tool in reduction chemistry in the last decade or so. This was largely triggered by the seminal work of Noyori and co-workers in the mid-1990s and is driven by its complementing chemistry to hydrogenation employing H-2. This Focus Review attempts to present a holistic overview on the advances in the area, focusing on the achievements recorded around the last three years. These include more-efficient and greener metal catalysts, catalysts that enable hydrogenation as well as transfer hydrogenation, biomimetic and organocatalysts, and their applications in the reduction of C=O, C=N, and C=C bonds. Also highlighted are efforts in the development of environmentally benign and reusable catalytic systems.
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