期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 3, 期 8-9, 页码 1238-1247出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200800094
关键词
arenes; chromophores; conjugation; luminescence; silicon
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [16GS0209]
The preparation of 4,5-dimethylsilylene- or 4,5-tetramethyldisilylene-bridged 9-silafluorenes was achieved by lithiation of 2,2',6,6'-tetrabromobiphenyls followed by silylation with dichlorodimethylsilane or 1,2-dichloro-1,1,2,2-tetramethyldisilane, respectively. X-ray analysis of the silylene-bridged silafluorene revealed that the molecular framework was perfectly planar and four Si-C(methyl) sigma bonds were completely orthogonal to the plane. Both the silicon atoms and the benzene rings were significantly deformed from the normal tetrahedral and hexagon shapes, respectively. The silicon bridge at the 4,5-positions was found to induce a red shift of the absorption and fluorescence spectra measured in cyclohexane, compared with 9-silafluorenes. It is remarkable that the disilylene-bridged silafluorene emitted blue light (lambda(em) = 450nm) with a large Stokes shift. The emission maxima of the silicon-bridged silafluorenes in thin films were similar to those measured in cyclohexane solution. DFT calculations suggested that introduction of the silicon bridge led to increases in both the HOMO and LUMO levels compared with 9-silafluorene.
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