期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 68, 页码 17986-17996出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803221
关键词
liquid exfoliation; metal-organic framework; nanosheet; supramolecular chemistry; two-dimensional materials
资金
- Ramsay Memorial Trust (JAF)
- Royal Society [RG170002]
- Engineering and Physical Sciences Research Council [EP/K503149/1]
- Sheffield University Research Experience Scheme
- Higher Committee for Education Development (HCED) in Iraq
- EPSRC [1797126] Funding Source: UKRI
The modular structure of metal-organic framework nanosheets (MONs) provides a convenient route to creating two-dimensional materials with readily tuneable surface properties. Here, the liquid exfoliation of two closely related layered metal-organic frameworks functionalised with either methoxy-propyl (1) or pentyl (2) pendent groups intended to bestow either hydrophilic or hydrophobic character to the resulting nanosheets is reported. Exfoliation of the two materials in a range of different solvents highlighted significant differences in their dispersion properties, as well as their molecular and nanoscopic structures. Exchange or loss of solvent was found to occur at the labile axial position of the paddle-wheel based MONs and DFT calculations indicated that intramolecular coordination by the oxygen of the methoxy-propyl pendant groups may take place. The nanoscopic dimensions of the MONs were further tuned by varying the exfoliation conditions and through liquid cascade centrifugation. Aqueous suspensions of the nanosheets were used as sensors to detect aromatic heterocycles with clear differences in binding behaviour observed and quantified.
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