期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 61, 页码 16395-16406出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803351
关键词
cage compounds; enzyme models; host-guest systems; iron; photochemistry
资金
- European Research Council (ERC Adv. NAT-CAT Reek)
The design of a biomimetic and fully base metal photocatalytic system for photocatalytic proton reduction in a homogeneous medium is described. A synthetic pyridylphosphole-appended [FeFe] hydrogenase mimic was encapsulated inside a supramolecular zinc porphyrin-based metal-organic cage structure Fe-4(Zn-L)(6). The binding is driven by the selective pyridine-zinc porphyrin interaction and results in the catalyst being bound strongly inside the hydrophobic cavity of the cage. Excitation of the capsule-forming porphyrin ligands with visible light while probing the IR spectrum confirmed that electron transfer takes place from the excited porphyrin cage to the catalyst residing inside the capsule. Light-driven proton reduction was achieved by irradiation of an acidic solution of the caged catalyst with visible light.
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