期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 60, 页码 16104-16112出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201802951
关键词
biomass; micron-sized carbon ribbons; NiCo2O4; nanosheets; nitrogen doping; supercapacitors
资金
- National Natural Science Foundation of China [51773165]
- Fundamental Research Funds for the Central Universities
- Young Talent Support Plan of Xi'an Jiaotong University
Increasing demand for effective energy-storage systems derived from low-cost and ecofriendly raw materials has aroused wide concern. In this contribution, we propose nitrogen-abundant amorphous micron-sized carbon ribbons (AMCRs) originating from biomass raupo as a novel substrate due to their specific quasi 2D morphologies and outstanding dispersion ability. Owing to the innate nitrogen atoms on the surface of AMCRs, ultrathin binary and ternary metal oxide (NiO, CoO, and NiCo2O4) nanosheets can be uniformly developed under benign conditions. These three composites were separately fabricated as electrodes for supercapacitors in a three-electrode system and exhibited favorable activities. Among them, the ternary metal oxide composites NiCo2O4@AMCRs delivered the supreme specific capacitance of 1691 Fg(-1) and best cycling stability (89% capacity retention over 10,000 cycles). Moreover, symmetric supercapacitors (NiCo2O4@AMCRs//NiCo2O4@AMCRs) were assembled inside sleeve devices with 2 M KOH aqueous electrolyte, which demonstrated admirable cyclic stability (79.1 % capacity retention over 8,000 cycles), and an excellent energy density of 26 Wh kg(-1) at the power density of 1.8 kW kg(-1).
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