期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 41, 页码 13146-13149出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404380
关键词
cross-coupling; C-S bond activation; organosulfur compounds; organozic compounds; palladium
资金
- MEXT [24106721, 25107002]
- JSPS [24685007, 26620081]
- Grants-in-Aid for Scientific Research [25620031, 24685007, 25107002, 24106721, 26620081] Funding Source: KAKEN
Cross-coupling of general aryl alkyl sulfides with arylzinc reagents proceeds smoothly, even at room temperature or below, with a palladium N-heterocyclic carbene (NHC) catalyst. When combined with reactions that are unique to organosulfurs, that is, the SNAr sulfanylation or Pummerer reaction, the cross-coupling offers interesting transformations that are otherwise difficult to achieve. An alkylsulfanyl group is preferentially converted whilst leaving the tosyloxy and chloro intact, which expands the variety of orthogonal cross-coupling.
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