期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 31, 页码 9524-9529出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403751
关键词
lanthanides; magnetic anisotropy; magnetic properties; single-molecule magnets
资金
- NSF [CHE-1010002]
- German Academic Exchange Service (DAAD)
- Direct For Mathematical & Physical Scien [1111900] Funding Source: National Science Foundation
- Division Of Chemistry [1111900] Funding Source: National Science Foundation
Single-molecule magnets comprising one spin center represent a fundamental size limit for spin-based information storage. Such an application hinges upon the realization of molecules possessing substantial barriers to spin inversion. Axially symmetric complexes of lanthanides hold the most promise for this due to their inherently high magnetic anisotropies and low tunneling probabilities. Herein, we demonstrate that strikingly large spin reversal barriers of 216 and 331 cm(-1) can also be realized in low-symmetry lanthanide tetraphenylborate complexes of the type [Cp-2*Ln(BPh4)] (Cp*=pentamethylcyclopentadienyl; Ln=Tb (1) and Dy (2)). The dysprosium congener showed hysteretic magnetization data up to 5.3 K. Further studies of the magnetic relaxation processes of 1 and 2 under applied dc fields and upon dilution within a matrix of [Cp-2*Y(BPh4)] revealed considerable suppression of the tunneling pathway, emphasizing the strong influence of dipolar interactions on the low-temperature magnetization dynamics in these systems.
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