期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 22, 页码 6608-6612出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402487
关键词
aromatics; diazo compounds; heterocyclic compounds; pseudohalogens; radicals
资金
- ANR (NeoACat)
- Region Basse-Normandie
An unprecedented spontaneous reactivity between diazonium salts and diboronic acid has been unveiled, leading to a versatile arylboronic acid synthesis directly from (hetero)arylamines. This fast reaction (35min overall) tolerates a wide range of functional groups and is carried out under very mild conditions. The radical nature of the reaction mechanism has been investigated.
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