期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 11, 页码 3212-3217出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304349
关键词
Biginelli reaction; heterogeneous catalysis; ionic liquids; manganese; mesoporous materials
资金
- Yasouj University
- Iran National Science Foundation (INSF)
The catalytic application of a novel manganese-containing periodic mesoporous organosilica with ionic-liquid framework (Mn@PMO-IL) in the Biginelli reaction was investigated. First, the Mn@PMO-IL nanocatalyst was prepared and characterized by TEM, SEM, X-ray photoelectron spectroscopy, and nitrogen-sorption analysis. The catalyst was then used in the one-pot Biginelli condensation of various aldehydes with urea and alkyl acetoacetates under solvent-free conditions. The corresponding dihydropyrimidone products were obtained in high to excellent yields and selectivities at short reaction times. Moreover, the catalyst was recovered and successfully reused many times with no notable decrease in activity and selectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据