期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 19, 页码 5559-5564出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304515
关键词
coordination polymer particles; hybrid nanostructures; metal-organic frameworks; MIL-88B; nanobamboos
资金
- National Leading Research Lab Program through a NRF grant [NRF-2012R1A2A1A03670409]
- MEST
A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {FexIn1-x}-MIL-88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {FexIn1-x}-MIL-88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In-MIL-88B (precise structure, {Fe0.06In0.94}-MIL-88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe-MIL-88B structure. The a and c cell parameters of {Fe0.06In0.94}-MIL-88B are calculated at 10.95 and 19.86 angstrom, respectively. These values of {Fe0.06In0.94}-MIL-88B are larger than those of pure Fe-MIL-88B owing to the large ionic size of In3+ within the framework.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据