Reversible Multistimuli-Response Fluorescent Switch Based on Tetraphenylethene-Spiropyran Molecules

Two tetraphenylethene (TPE)-functionalized spiropyran (SP) molecules with very similar structure were designed and synthesized. The two molecules exhibit aggregation-induced emission (AIE) properties, as well as multistimuli-responsive color-changing properties, such as photochromism and acidchromism. The investigation of their different photochromic and acidchromic characteristics and dual-response fluorescent switch during isomerization indicated that the different link position between TPE and SP will significantly affect the extended -conjugated system, resulting in completely different photochromic and acidchromic properties.