期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 28, 页码 8536-8540出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403143
关键词
alkaloids; C-H bond activation; natural products; palladium; stereoselective catalysis
资金
- Deutsche Forschungsgemeinschaft [KN 240/16-1]
The boronic acid-catalyzed annulation of citral opens up a short route to oxygenated cyclized monoterpenoid pyranocarbazole alkaloids. Thus, murrayamine-D is available in only three steps and 55% overall yield from the corresponding carbazole precursor.
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