期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 2, 页码 526-530出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405505
关键词
C3N4; carbon nitride; fluoroalkylation; heterogeneous photoredox catalysis; trifluoromethylation; visible light
资金
- Cluster of Excellence UniCat
- Deutsche Forschungsgemeinschaft
- Light2Hydrogen Project of the BMBF [03IS2071D]
Heterogeneous catalysis for trifluoromethylations and perfluoroalkylations has been performed. Through the usage of cheap, metal-free and recyclable mesoporous graphitic carbon nitride (mpg-CN) it was possible to fluoroalkylate various arenes by the reductive activation of sulfonyl chlorides with visible light. Thus, we were able to demonstrate the robustness and versatility of mpg-CN as a photoredox catalyst beyond water splitting and the activation of oxygen.
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