期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 35, 页码 11078-11083出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402359
关键词
batteries; energy storage; iron; nanostructures; porous materials; spray pyrolysis
资金
- National Research Foundation of Korea (NRF) - Korea government (MEST) [2012R1A2A2A02046367]
- Energy Efficiency & Resources Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Ministry of Trade, Industry & Energy, Republic of Korea [201320200000420]
Macroporous Fe3O4/carbon composite and core-shell Fe3O4@carbon composite microspheres have been prepared by means of one-pot spray pyrolysis. The addition of polystyrene (PS) nanobeads to a spray solution containing an iron salt and poly(vinylpyrrolidone) (PVP) led to macroporous Fe3O4/carbon composite microspheres, the carbon and iron components of which are uniformly distributed over the entire composite microsphere. The pore-size distribution curve for the macroporous Fe3O4/carbon composite shows distinct peaks at around 10 and 80 nm. An electrode prepared from the macroporous Fe3O4/carbon composite microspheres showed better cycling and rate performances than an electrode formed from core-shell Fe3O4@carbon composite microspheres. The initial discharge and charge capacities of the macroporous Fe3O4/carbon composite microsphere electrode were determined to be 1258 and 908 mA h g(-1) at 2 Ag-1, respectively, and the corresponding initial coulombic efficiency was 72%. The composite microsphere electrode cycled 500 times at 5 Ag-1 showed a high discharge capacity of 733 mA h g(-1).
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