期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 38, 页码 12004-12008出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403501
关键词
copper; hydrocarbon storage; hydrophobicity; metal-organic frameworks; water purification
资金
- National Basic Research Program of China [2012CB821706, 2013CB834803]
- National Natural Science Foundation of China [21171114, 91222202]
A novel hydrophobic metal-organic framework (MOF), namely Cu2L (L=3,3', 5,5'-tetraethyl-4,4'-bipyrazolate), is synthesized through a stepwise method, and exhibits an unprecedented 3,4-c net. The exceptionally thermal, chemical, and air stability of this MOF, especially in water and under acidic or basic conditions, and its selective and fast sorption capacity for hydrocarbons over water warrant its direct use for efficient removal of trace organic wastes (e. g. benzene, toluene, xylene, and mixtures thereof) from contaminated water.
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