期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 29, 页码 8918-8922出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403294
关键词
allene; carbometalation; copper; enolate; Grignard reagent
Carboxylate anions, dianions and ester enolates provide simultaneous protection and activation for directed carbometalation reactions. Advantage can be taken of the bis-carbanionic character of the intermediate for further controlled C-C bond forming reactions.
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