期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 47, 页码 15303-15308出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402855
关键词
coordination polymers; dynamic frameworks; host-guest systems; separation; sorption
资金
- CSIR
- DAE [2011/20/37C/06/BRNS]
- DST [GAP/DST/CHE-12-0083]
A 3D dynamic coordination framework with an electron-deficient pore surface has been synthesized by using Zn-II (having a variable coordination number) and a predesigned flexible pi-electron-deficient core-based ligand, exhibiting chemical separations based on pore surface functionalization (pi Lewis acidic pore surfaces and open metal sites) and framework flexibility, giving rise to a unique smart guest-responsive material.
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