期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 38, 页码 12234-12238出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403144
关键词
aerobic oxidation; amidation; amides; C-C activation; C-N cleavage
资金
- NSFC [U1162109, 21172062, 21373080]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1238]
- Program for New Century Excellent Talents in Universities [NCET-10-0371]
- Fundamental Research Funds for the Central Universities (Hunan University)
A copper-catalyzed aerobic oxidative amidation reaction of inert C-C bonds with tertiary amines has been developed for the synthesis of tertiary amides, which are significant units in many natural products, pharmaceuticals, and fine chemicals. This method combines C-C bond activation, C-N bond cleavage, and C-H bond oxygenation in a one-pot protocol, using molecular oxygen as the sole oxidant without any additional ligands.
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