期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 6, 页码 2603-2612出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405291
关键词
charge transfer; emissive materials; isocyanoborate; phosphorescence; rhenium
资金
- Hong Kong University Grants Committee Area of Excellence [AoE/P-03-08]
- RGC GRF from Research Grants Council of the Hong Kong SAR, China [CityU 101212]
- University Postgraduate Studentship
- Research Tuition Scholarship
A new series of neutral isocyanoborato rhenium(I) diimine complexes [Re(CO)(3)(N<^>N)(CNBR3)], where N<^>N=bpy, 4,4-Me(2)bpy, phen, 4,7-Me(2)phen, 2,9-Me(2)phen, 3,4,7,8-Me(4)phen; R=C6F5, C6H5, Cl, 4-ClC6H4, 3,5-(CF3)(2)C6H3, with various isocyanoborate and diimine ligands of diverse electronic and steric nature have been synthesized and characterized. The X-ray crystal structures of six complexes have also been determined. These complexes displayed intense bluish green to yellow phosphorescence at room temperature in dichloromethane solution. The photophysical and electrochemical properties of these complexes had been investigated. To elucidate the electronic structures and transitions of these complexes, DFT and TD-DFT calculations have been performed, which revealed that the lowest-energy electronic transition associated with these complexes originates from a mixture of MLCT [d(Re)*(N<^>N)] and LLCT [(CNBR3)*(N<^>N)] transitions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据