期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 52, 页码 17287-17291出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405174
关键词
C-H activation; hydroarylation; olefins; platinum; (pyridyl)pyrrolide
资金
- NSF [CHE-1012045]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1012045] Funding Source: National Science Foundation
Pt-II complexes containing unsymmetrical (pyridyl)pyrrolide ligands are shown to catalyze the hydroarylation of unactivated alkenes with selectivity for the anti-Markovnikov product. Substitution on the pyrrolide portion of the ligand allows effective tuning of the selectivity to anti-Markovnikov alkylarene products, whereas substitution on the pyridyl portion can promote competitive alkenylarene production.
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