期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 51, 页码 16888-16898出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404342
关键词
cluster; germanium; platinum; pyramidalization; tin
资金
- Deutsche Forschungsgemeinschaft
- Australian Research Council
- Supercomputer Center of the University of Guanajuato for providing computer time through CONACyT [123732]
We present the isolation of the first mononuclear dihalogermylene, and mono- and dinuclear stannylene complexes of transition metals. These exhibit exceptionally pyramidalized Group 14 centers. Additionally, removal of the halide substituents from the Ge/Sn atom was successfully performed in two ways, halide abstraction and reduction, leading to a variety of unusual structural motifs.
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