期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 13, 页码 3616-3620出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304615
关键词
boration; density functional theory; diboron reagents; nucleophilic boron
资金
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2010-16226, CTQ2008-06549-C02-01/BQU]
- Direccio General de Recerca (DGR) of the Autonomous Government of Catalonia [2009SGR462, XRQTC]
- URV
Activating the non-symmetrical BpinBdan diboron reagent with alkoxide leads to the formation of two possible adducts: MeO(-)BpinBdan or MeO(-)BdanBpin. Experimental and theoretical investigation confirms that the MeO(-)Bpin interaction is preferred and thus selective formation of a CBdan bond upon reaction with an activated CC bond.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
