期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 34, 页码 10626-10631出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304461
关键词
azaacenes; electronic materials; low LUMO; polycyclic aromatic hydrocarbons; pyrene
资金
- POLYMAT
- Basque Science Foundation for Science (Ikerbasque)
- Freiburg Institute for Advanced Studies (Junior Research Fellowship)
- Deutsche Forschungsgemeinschaft [AU 373/3-1, MA 5215/4-1]
- Gobierno de Espana (Ministerio de Economia y Competitividad) [MAT2012-35826]
- Diputacion Foral de Guipuzcoa
- European Union [618247]
A series of pyrene-fused azaacenes with four and six linearly fused rings that possess LUMO levels between -3.7 and -4.3 eV is reported. These LUMO values are remarkably lower than those typically observed for pyrene-fused azaacenes, even for systems with sixteen linearly fused rings, and are comparable to those observed for state-of-the-art n-azaacenes.
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