期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 8, 页码 2232-2243出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304069
关键词
dipolarity; ionic liquids; polarity scales; polarizability; solvatochromism
资金
- DFG [SPP 1191]
- Fond der Chemischen Industrie
The four empirical solvent polarity parameters according to the Catalan scalesolvent acidity (SA), solvent basicity (SB), solvent polarizability (SP), and solvent dipolarity (SdP)of 64 ionic liquids (ILs) were determined by the solvatochromic method. The SA parameter was determined solely by using [Fe-II(1,10-phenanthroline)(2)(CN)(2)] (Fe), the SB parameter by using the pair of structurally comparable dyes 3-(4-amino-3-methylphenyl)-7-phenylbenzo[1,2-b:4,5-b]difuran-2,6-dione (ABF) and 3-(4-N,N-dimethylaminophenyl)-7-phenylbenzo[1,2-b:4,5-b]-difuran-2,6-dione (DMe-ABF), and the SP and SdP parameters by using the homomorphic pair of 4-tert-butyl-2-(dicyanomethylene)-5-[4-(diethylamino)benzylidene]-(3)-thiazoline (Th) and 2-[4-(N,N-dimethylamino)benzylidene]malononitrile (BMN). The separation of SP and SdP for a set of 64 various ILs was performed for the first time. Correlation analyses of SP with physicochemical data related to ionization potentials of anions of ILs as well as with theoretical data show the correctness of the applied method. The found correlations of the Catalan parameters with each other and with the alkyl-chain length of 1-alkyl-3-methylimidazolium-type ILs gives new information about interactions within ILs. An analytical comparison of the determined Catalan parameters with the established Kamlet-Taft parameters and the Gutmann acceptor and donor numbers is also presented.
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