期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 6, 页码 2335-2338出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405407
关键词
asymmetric catalysis; cycloaddition; nitroalkenes; palladium catalyst; vinylcyclopropane
资金
- National Natural Science Foundation of China [21372224, 21232008]
- Ministry of Science and Technology [2011CB808600]
- Chinese Academy of Sciences
An enantioselective [3+2] cycloaddition of vinyl cyclopropane derived from 1,3-indanedione with nitroalkenes catalyzed by palladium(0) with a chiral bis(tert-amine) ligand was developed in high yields with good diastereoselectivities and excellent enantioselectivities. The resulting bis(tert-amine)-palladium complex proved to be a highly efficient catalyst for this cycloaddition.
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