期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 38, 页码 12061-12065出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403447
关键词
copper; dual catalyst; enone; rhenium; trifluoromethyl
资金
- RIKEN
- NOVARTIS Foundation (Japan) for the Promotion of Science
Trifluoromethylation of propargylic alcohols to provide (Z)-alpha-trifluoromethylated enones and beta-unsubstituted alpha-trifluoromethylated enones proceeded with high yield and selectivity in the presence of CuI/Re2O7. The Z isomer was formed under kinetic control, though it is less stable than the E isomer in terms of steric repulsion.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据