期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 18, 页码 5388-5396出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304538
关键词
antiferromagnetism; exchange interactions; ferromagnetism; heterocycles; radicals
资金
- University of Cyprus
- Cyprus Research Promotion Foundation [YGammaEIA/BIOSigma/0308(BIE)/13, NEKYPi/0308/02, ANA BAThetaMISigmaH/0308/32]
- CFI
- ORF
- Israeli Science Foundation
1,3,7,8-Tetraphenyl-4,8-dihydro-1H-imidazolo[4,5g][1,2,4]benzotriazin-4-yl (5), 8-(4-bromophenyl)-1,3,7-triphenyl-4,8-dihydro-1H-imidazolo[4,5g][1,2,4]benzotriazin-4-yl (6), and 8-(4-methoxyphenyl)-1,3,7-triphenyl-4,8-dihydro-1H-imidazolo[4,5g][1,2,4]benzotriazin-4-yl (7) were characterized by using X-ray diffraction crystallography, variable-temperature magnetic susceptibility studies, and DFT calculations. Radicals 5-7 pack in 1D stacks made of radical pairs with alternate short and long interplanar distances. The magnetic susceptibility ( vs. T) of radicals 5 and 6 exhibit broad maxima at (50 +/- 2) and (50 +/- 4)K, respectively, and are interpreted in terms of an alternating antiferromagnetic Heisenberg linear chain model with average exchange-interaction values of J=-31.3 and -35.4cm(-1) (g(solid)=2.0030 and 2.0028) and an alternation parameter a=0.15 and 0.38 for 5 and 6, respectively. However, radical 7 forms 1D columns of radical pairs with alternating distances; one of the interplanar distances is significantly longer than the other, which decreases the magnetic dimensionality and leads to discrete dimers with a ferromagnetic exchange interaction between the radicals (2J=23.6cm(-1), 2zJ=-2.8cm(-1), g(solid)=2.0028). Magnetic exchange-coupling interactions in 1,2,4-benzotriazinyl radicals are sensitive to the degree of slippage and inter-radical separation, and such subtle changes in structure alter the fine balance between ferro- and antiferromagnetic interactions.
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