期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 18, 页码 5231-5236出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304164
关键词
aryl halides; catalysis; diaryl ether; nucleophilic aromatic substitution; transition metals
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Fonds de recherche du Quebec-Nature et Technologies (FRQNT)
- Conseil Franco-Quebecois de Cooperation Universitaire (CFQCU)
- Centre in Green Chemistry and Catalysis (CGCC)
- Universite Laval
- Centre National de la Recherche Scientifique (CNRS)
- Agence Nationale de la Recherche (ANR)
- Ecole Nationale Superieure de Chimie de Montpellier (ENSCM)
- FRQNT
- CGCC
A study on the arylation of heteroatom nucleophiles by using activated haloarenes, with or without metal catalysts, is reported. A discussion concerning the involvement of traces of metals is presented, supported by an unexpected ''ligand'' effect in the absence of added metal catalysts. We believe that the frontier between nucleophilic aromatic substitution and catalysis will likely prove to be much harder to delimit than is generally thought.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据