4.6 Article

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of C-H Bond Functionalization

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 51, 页码 16830-16845

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404537

关键词

alkenes; alkynes; fluorination; radical reactions; trifluoromethylation

资金

  1. INSA Rouen
  2. Rouen University
  3. CNRS
  4. EFRD
  5. Labex SynOrg [ANR-11-LABX-0029]
  6. Region Haute-Normandie (CRUNCh network)

向作者/读者索取更多资源

The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot of attention and particularly the direct functionalization of alkenes and alkynes. This review will highlight the major progress recently made in that field, with a focus on photocatalyzed transformations, base-promoted processes, and transition metal-catalyzed functionalization of alkenes and alkynes. Special attention will be paid to explanations of the reaction mechanisms.

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