期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 51, 页码 16830-16845出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404537
关键词
alkenes; alkynes; fluorination; radical reactions; trifluoromethylation
资金
- INSA Rouen
- Rouen University
- CNRS
- EFRD
- Labex SynOrg [ANR-11-LABX-0029]
- Region Haute-Normandie (CRUNCh network)
The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot of attention and particularly the direct functionalization of alkenes and alkynes. This review will highlight the major progress recently made in that field, with a focus on photocatalyzed transformations, base-promoted processes, and transition metal-catalyzed functionalization of alkenes and alkynes. Special attention will be paid to explanations of the reaction mechanisms.
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