期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 20, 期 1, 页码 93-97出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201303641
关键词
beta-ketoesters; asymmetric catalysis; copper; pincer ligands; trifluoromethylthiolation
资金
- University of Heidelberg
- State of Baden-Wurttemberg
- BASF SE
The enantioselective trifluoromethylthiolation of -ketoesters using chiral copper-boxmi complexes as catalysts is reported. A number of -SCF3-substituted -ketoesters have been obtained with up to >99% enantiomeric excess (ee), and the trifluoromethylthiolated products were then transformed diastereoselectively to -SCF3--hydroxyesters with two adjacent quaternary stereocenters.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
