期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 45, 页码 15261-15266出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201303248
关键词
carbenes; difluorocyclopropanation; difluoro-olefination; fluorine; ylides
资金
- National Natural Science Foundation [21032006, 21172240]
- 973 Program of China [2012CBA01200]
- Chinese Academy of Sciences
The interconversion between difluoromethylene ylide and difluorocarbene is described. The difluoromethylene ylide precursor, Ph3P+CF2CO2-, could be turned into an efficient difluorocarbene reagent, whereas the classical difluorocarbene reagents, HCF2Cl and FSO2CF2CO2TMS, could generate highly reactive difluoromethylene ylide. Thus the Wittig difluoro-olefination and difluorocyclopropanation could be selectively realized by using the same reagent. In addition, the ylides obtained from different carbene sources showed different reactivity in Wittig reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据