期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 20, 页码 6443-6450出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201204572
关键词
aerobic reaction; cross-coupling; platinum; radicals; visible-light catalysis
资金
- Ministry of Science and Technology of China [2009CB220008, 2013CB834505, 2013CB834804]
- National Natural Science Foundation of China [21090343, 91027041]
- Knowledge Innovation Program of the Chinese Academy of Sciences
Thanks to the superior redox potential of platinum(II) complex compared with that of Ru(bpy)32+ in the excited state, an efficient and selective visible-light-induced CDC reaction has been developed by using a catalytic amount (0.25%) of 1. With the aid of FeSO4 (2equiv), the corresponding amide could not be detected under visible-light irradiation (=450nm), but the desired cross-coupling product was exclusively obtained under ambient air conditions. A spectroscopic study and product analysis revealed that the CDC reaction is initiated by photoinduced electron-transfer from N-phenyltetrahydroisoquinoline to the complex. An EPR (electron paramagnetic resonance) experiment provides direct evidence on the generation of superoxide radical anion (O2.) rather than singlet oxygen (1O2) under irradiation of the reaction system, in contrast to that reported in the literature. Combined, the photoinduced electron-transfer and subsequent formation of superoxide radical anion (O2.) results in a clean and facile transformation.
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