期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 30, 页码 9866-9874出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201300037
关键词
carbon; coaxial nanocables; electrochemistry; lithium-ion batteries; nanotubes
资金
- Startup Foundation of the China Academy of Engineering Physics, Institute of Chemical Materials [KJCX201301]
By using carbon nanotubes (CNTs) as a shape template and glucose as a carbon precursor and structure-directing agent, CNT@Fe3O4@C porous core/sheath coaxial nanocables have been synthesized by a simple one-pot hydrothermal process. Neither a surfactant/ligand nor a CNT pretreatment is needed in the synthetic process. A possible growth mechanism governing the formation of this nanostructure is discussed. When used as an anode material of lithium-ion batteries, the CNT@Fe3O4@C nanocables show significantly enhanced cycling performance, high rate capability, and high Coulombic efficiency compared with pure Fe2O3 particles and Fe3O4/CNT composites. The CNT@Fe3O4@C nanocables deliver a reversible capacity of 1290mAhg(-1) after 80cycles at a current density of 200mAg(-1), and maintain a reversible capacity of 690mAhg(-1) after 200cycles at a current density of 2000mAg(-1). The improved lithium storage behavior can be attributed to the synergistic effect of the high electronic conductivity support and the inner CNT/outer carbon buffering matrix.
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