期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 41, 页码 13956-13961出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201300890
关键词
olefins; palladium; polymerization; Wacker reaction; water chemistry
资金
- National Natural Sciences Foundation of China [21174159, 21121062]
- Major State Basic Research Development Program [2009CB825300]
- Chinese Academy of Sciences
By a reasonable combination of the Wacker reaction and olefin polymerization processes, water proves to be an excellent activator for the palladium(II)-catalyzed polymerization of ethylene and it provides a safe, environmental-friendly and handy initiator for olefin polymerization. The activity of the olefin polymerization is comparable to reactions catalyzed by the corresponding alkylated cationic palladium complexes.
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