期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 41, 页码 13925-13928出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201301988
关键词
alkenylation; catalysis; CH activation; cross-dehydrogenative coupling; reaction mechanisms; ruthenium
资金
- European Research Council under the European Community [307535]
- Chinese Scholarship Council
Cationic ruthenium(II) complexes enabled oxidative alkenylations of phenols bearing easily cleavable directing groups. The optimized catalytic system allowed twofold C-H bond activations with excellent chemo-, site-, and diastereoselectivities. The double C-H functionalization process proceeded efficiently in an aerobic fashion under an atmosphere of ambient air. Detailed mechanistic studies were performed and provided strong support for an initial reversible C-H bond activation by the formation of six-membered ruthenacycles as the key intermediates.
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