期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 21, 页码 6739-6745出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201300204
关键词
-amino acids; asymmetric catalysis; azomethine ylides; cycloaddition; silver
资金
- Fundamental Research Funds for the Central Universities
- Shanghai Committee of Science and Technology [11DZ2260600]
- National Natural Science Foundation of China [21172068]
- Shanghai Education Development Foundation [09SG28]
The first catalytic enantioselective 1,3-dipolar cycloaddition of azomethine ylides to -aminoacrylate catalyzed by a AgOAc/ferrocenyl oxazolinylphosphine (FOXAP) system was developed, which exhibits excellent exo- and enantioselectivity (9299%ee). This process provides efficient access to useful 4-aminopyrrolidine-2,4-dicarboxylic acid (APDC)-like compounds containing a unique quaternary -amino acid unit.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
