期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 11, 页码 3534-3541出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201204596
关键词
click chemistry; copper; cycloaddition; metal alkynes; metal azides; polymetallic complexes
资金
- Spanish MINECO [CTQ-2010-20414C02/ BQU]
- Consolider Ingenio [CSD2007-00006]
- Comunidad de Madrid [P2009/PPQ1634-AVANCAT]
CuI-catalyzed 1,3-cycloaddition of azides and alkynes (CuAAC) is one of the most powerful synthetic methodologies known. However, its use to prepare well-defined multimetallic structures is underdeveloped. Apart from the applications of this reaction to anchor different organometallic reagents to surfaces, polymers, and dendrimers, only isolated examples of CuAAC with metal1-alkyne and metalazide complexes to prepare multimetal entities have been reported. This concept sketches the potential of these reactions not only to prepare a la carte multimetal 1,2,3-triazole derivatives, but also to discover new and unprecedented reactions.
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