期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 51, 页码 17464-17471出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201302226
关键词
heterogeneous catalysis; hydrogen transfer; palladium; synthetic methods; thioethers
资金
- Consolider-Ingenio (project MULTICAT)
- Spanish MICINN [MAT2011-28009]
- Generalitat Valenciana [PROMETEO/2008/130]
- Programa Severo Ochoa
- Consejo Superior de Investigaciones Cientificas
Palladium on magnesium oxide is able to allow a one-pot reaction to synthesize thioethers from thiols and aldehydes formed in situ from the respective alcohol by means of a borrowing hydrogen method. The reaction is initiated by dehydrogenation of the alcohol to give a palladium hydride intermediate and an aldehyde. The latter reacts with a thiol involving most probably the intermediacy of a thionium ion RCHS+R, which can be reduced in situ by the metal hydride to afford thioethers.
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