期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 18, 期 43, 页码 13566-13579出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201200783
关键词
actinides; bond theory; intermetalloids; lanthanides; metal-metal interactions
资金
- Deutsche Forschungsgemeinschaft (DFG) [KE756/21-1]
Metalmetal bonding in heterobimetallic complexes is of fundamental interest due to its implications to both bonding theory and new reactivities. In this Concept, structurally authenticated molecular compounds with direct bonds between rare-earth metals or actinoids and transition or main group metals are summarized. Special attention is given to the use of bond polarity as a tool for designing molecular intermetalloids incorporating rare-earth atoms and transition metals.
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