期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 18, 期 22, 页码 6928-6934出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201200062
关键词
conjugation; cross-coupling; fluorescence; OLEDs; oligomers
资金
- National Science Fund for Distinguished Young Scholars of China [51125013]
- National Basic Research Program of China (973 Program) [2009CB623602]
- National Natural Science Foundation of China [90922020, 61177022]
- Fundamental Research Funds for the Central Universities of China
A series of starburst oligomers (T1T3) that contained a fully diarylmethene-bridged triphenylamine core and oligofluorene arms were designed and synthesized through Suzuki cross-coupling reactions. Their thermal, photophysical, and electrochemical properties were also investigated. These materials showed high glass transition, in the range of 123129?degrees C, and good film-forming abilities. They displayed deep-blue emission both in solution and as thin films. Solution-processed devices based on these oligomers exhibited highly efficient deep-blue electroluminescence and the device performances were significantly enhanced with the extension of the oligofluorene arms. The double-layered device that contained T3 as an emitter showed a maximum current efficiency of 3.83 cd?A-1 and a maximum external quantum efficiency of 4.19?% with CIE coordinates of (0.16, 0.09), which are among the highest values for undoped deep-blue OLEDs that are based on solution-processable starburst oligomers.
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