期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 3, 页码 974-980出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201202940
关键词
adsorption; electrochemistry; fuel cells; oxygen-reduction reaction; porous organic frameworks
资金
- CSIR [NWP0022, NWP0021]
- DST [SR/S1/IC-22/2009]
- BRNS [2011/37C/44/BRNS]
Porous nitrogen-rich carbon (POF-C-1000) that was synthesized by using a porous organic framework (POF) as a self-sacrificing host template in a nanocasting process possessed a high degree of graphitization in an ordered structural arrangement with large domains and well-ordered arrays of carbon sheets. POF-C-1000 exhibits favorable electrocatalytic activity for the oxygen-reduction reaction (ORR) with a clear positive shift of about 40 mV in the onset potential compared to that of a traditional, commercially available Pt/C catalyst. In addition, irrespective of its moderate surface area (785 m2?g-1), POF-C-1000 showed a reasonable H2 adsorption of 1.6 wt?% (77 K) and a CO2 uptake of 3.5 mmol?g-1 (273 K).
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