期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 18, 期 45, 页码 14392-14405出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201200510
关键词
conformation analysis; galactoglucomannan; molecular recognition; NMR spectroscopy; oligosaccharide synthesis
资金
- Academy of Finland [121334, 121335]
- MICINN [CTQ2009-08536]
- EC
- Harry Elvings Legat
- Academy of Finland (AKA) [121335, 121334] Funding Source: Academy of Finland (AKA)
Galactoglucomannan (GGM) is a polysaccharide mainly consisting of mannose, glucose, and galactose. GGM is the most abundant hemicellulose in the Norway spruce (Picea abies), but is also found in the cell wall of flax seeds, tobacco plants, and kiwifruit. Although several applications for GGM polysaccharides have been developed in pulp and paper manufacturing and the food and medical industries, attempts to synthesize and study distinct fragments of this polysaccharide have not been reported previously. Herein, the synthesis of one of the core trisaccharide units of GGM together with a less-abundant tetrasaccharide fragment is described. In addition, detailed NMR spectroscopic characterization of the model compounds, comparison of the spectral data with natural GGM, investigation of the acetyl-group migration phenomena that takes place in the polysaccharide by using small model compounds, and a binding study between the tetrasaccharide model fragment and a galactose-binding protein (the toxin viscumin) are reported.
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