期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 19, 期 1, 页码 40-62出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201203072
关键词
bond activation; homogeneous catalysis; oxidative addition; silicon-based ligands; zwitterionic compounds
资金
- Deutsche Forschungsgemeinschaft
- Cluster of Excellence UniCat
This account is a review on the synthesis and transition-metal coordination chemistry of N-heterocyclic silylenes (NHSi's) over the last 20 years till the present time (2012). Recently, fascinating and novel synthetic methods have been developed to access transition-metal-NHSi complexes as an emerging class of compounds with a wealth of intriguing reactivity patterns. The striking influence of coordinating NHSi's to transition-metal complex fragments affording different reactivities to the free NHSi is a connecting theme (leitmotif) through-out the review, and highlights the potential of these compounds which lie at the interface of contemporary main-group and classical organometallic chemistry towards new molecular catalysts for small-molecule activation.
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