期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 18, 期 19, 页码 5970-5978出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201102653
关键词
electrochemistry; nanoparticles; niobium; oxynitrides; solid-state reactions
资金
- European Commission Research Directorate General [FP7-NMP-2008-1]
The decomposition reaction of niobium(V) oxytrichloride ammoniate to the oxynitride of niobium in the 5+ oxidation state was developed in a methodological way. By combining elemental analysis, Rietveld refinements of X-ray and neutron diffraction data, SEM and TEM, the sample compound was identified as approximately 5 nm-diameter particles of NbO1.3(1)N0.7(1) crystallizing with baddeleyite-type structure. The thermal stability of this compound was studied in detail by thermogravimetric/differential thermal analysis and temperature-dependent X-ray diffraction. Moreover, the electrochemical uptake and release by the galvanostatic cycling method of pure and carbon-coated NbO1.3(1)N0.7(1) versus lithium was investigated as an example of an Li-free transition-metal oxynitride. The results showed that reversible capacities as high as 250 and 80 A?h?kg-1 can be reached in voltage ranges of 0.053 and 13 V, respectively. Furthermore, a plausible mechanism for the chargedischarge reaction is proposed.
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