期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 15, 页码 4307-4312出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201003060
关键词
iron; oxygen; peroxides; radical reactions; water
资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Grants-in-Aid for Scientific Research [22106513] Funding Source: KAKEN
A mild and practical oxyarylation of alkenes by oxidative radical addition has been developed by using aerobic oxidation of hydrazine compounds. The use of a catalytic amount of potassium ferrocyanide trihydrate (K-4[Fe(CN)(6)]center dot 3H(2)O) and water accelerated this radical reaction to give peroxides or alcohols from simple alkenes in good yields. The environmentally friendly and economical radical reactions were achieved at room temperature in the presence of iron catalyst, oxygen gas, and water. A method involving aniline as a radical precursor is also described.
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