期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 17, 期 14, 页码 3812-3822出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201100260
关键词
cycloaddition; heterocycles; nitrogen; oxyallyl cations; regioselectivity
资金
- NIH [GM066055]
The use of heteroatom-substituted oxyallyl cations in (4+3) cycloadditions has had a tremendous impact on the development of cycloaddition chemistry. Extensive efforts have been exerted toward investigating the effect of oxygen, sulfur, and halogen substituents on the reactivity of oxyallyl cations. Most recently, the use of nitrogen-stabilized oxyallyl cations has gained prominence in the area of (4+3) cycloadditions. The following article will provide an overview of this concept utilizing nitrogen-stabilized oxyallyl cations.
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