期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 18, 期 5, 页码 1502-1511出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201102598
关键词
organic photovoltaics; organic solar cells; platinum; solution processing; synthetic methods; voltammetry
资金
- University Grants Committee [AoE/P-03/08]
- Hong Kong Baptist University [FRG2/09 10/091]
- Hong Kong Research Grants Council [HKBU202410]
- State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
Four new solution-processible small-molecular platinum(II)bis(aryleneethynylene) complexes consisting of benzothiadiazole as the electron acceptor and triphenylamine and/or thiophene as the electron donor were conveniently synthesized and characterized by physicochemical and computational methods, and utilized as the electron-donor materials in the fabrication of solution-processed bulk heterojunction (BHJ) solar cells. The effect of different electron-donor groups in these small molecules on the optoelectronic and photovoltaic properties was also examined. The optical and time-dependent density functional theory studies showed that the incorporation of stronger electron-donor groups significantly enhanced the solar-absorption abilities of the complexes. These molecular complexes can serve as good electron donors for fabricating BHJ devices by blending them with the [6,6]-phenyl-C71-butyric acid methyl ester (PC70BM) as the electron acceptor. The best power conversion efficiency of 2.37% was achieved with the open-circuit voltage of 0.83 V, short-circuit current density of 7.10 mAcm(-2) and fill factor of 0.40 under illumination of an AM 1.5 solar-cell simulator. The spin-coated thin films showed p-channel field-effect charge transport with hole mobilities of up to 2.4 x 10(-4) cm(2) V-1 s(-1) for these molecules. The present work illuminates the potential of well-defined organometallic complexes in developing light-harvesting small molecules for efficient power generation in organic photovoltaics implementation.
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